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Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization

The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)‐catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Carreras, Javier, Kirillova, Mariia S., Echavarren, Antonio M.
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5053274/
https://ncbi.nlm.nih.gov/pubmed/27119910
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601834
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