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Prediction of response factors for gas chromatography with flame ionization detection: Algorithm improvement, extension to silylated compounds, and application to the quantification of metabolites

We previously showed that the relative response factors of volatile compounds were predictable from either combustion enthalpies or their molecular formulae only 1. We now extend this prediction to silylated derivatives by adding an increment in the ab initio calculation of combustion enthalpies. Th...

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發表在:J Sep Sci
Main Authors: de Saint Laumer, Jean‐Yves, Leocata, Sabine, Tissot, Emeline, Baroux, Lucie, Kampf, David M., Merle, Philippe, Boschung, Alain, Seyfried, Markus, Chaintreau, Alain
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2015
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5049641/
https://ncbi.nlm.nih.gov/pubmed/26179324
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/jssc.201500106
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