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Covalent bonds against magnetism in transition metal compounds

Magnetism in transition metal compounds is usually considered starting from a description of isolated ions, as exact as possible, and treating their (exchange) interaction at a later stage. We show that this standard approach may break down in many cases, especially in 4d and 5d compounds. We argue...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Streltsov, Sergey V., Khomskii, Daniel I.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5035886/
https://ncbi.nlm.nih.gov/pubmed/27601669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1606367113
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