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Does Thermal Breathing Affect Collision Cross Sections of Gas-Phase Peptide Ions? An Ab Initio Molecular Dynamics Study

Ab initio molecular dynamics (AIMD) with density functional theory (DFT) was applied to explore conformational motions and collision cross sections (Ω) of folded (2) and extended (7) conformers of doubly charged peptide ions, (Ala–Ala–Leu–Arg + 2H)(2+), in the gas phase at 300 and 473 K. The experim...

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Detalhes bibliográficos
Publicado no:J Phys Chem Lett
Main Authors: Pepin, Robert, Petrone, Alessio, Laszlo, Kenneth J., Bush, Matthew F., Li, Xiaosong, Tureček, František
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5032842/
https://ncbi.nlm.nih.gov/pubmed/27389035
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.6b01187
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