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Saddle point localization of molecular wavefunctions

The quantum mechanical description of isomerization is based on bound eigenstates of the molecular potential energy surface. For the near-minimum regions there is a textbook-based relationship between the potential and eigenenergies. Here we show how the saddle point region that connects the two min...

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Detalles Bibliográficos
Publicado en:Sci Rep
Main Authors: Mellau, Georg Ch., Kyuberis, Alexandra A., Polyansky, Oleg L., Zobov, Nikolai, Field, Robert W.
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group 2016
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5024097/
https://ncbi.nlm.nih.gov/pubmed/27629262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep33068
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