Thermodynamic Insight in the High-Pressure Behavior of UiO-66: Effect of Linker Defects and Linker Expansion

[Image: see text] In this Article, we present a molecular-level understanding of the experimentally observed loss of crystallinity in UiO-66-type metal–organic frameworks, including the pristine UiO-66 to -68 as well as defect-containing UiO-66 materials, under the influence of external pressure. Th...

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Publicado no:Chem Mater
Main Authors: Rogge, Sven M. J., Wieme, Jelle, Vanduyfhuys, Louis, Vandenbrande, Steven, Maurin, Guillaume, Verstraelen, Toon, Waroquier, Michel, Van Speybroeck, Veronique
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5006632/
https://ncbi.nlm.nih.gov/pubmed/27594765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemmater.6b01956
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