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Ruthenium-Catalyzed C–H Bond Activation Approach to Azolyl Aminals and Hemiaminal Ethers, Mechanistic Evaluations, and Isomer Interconversion

C(sp(3))–N bond-forming reactions between benzotriazole and 5,6-dimethylbenzotriazole with N-methylpyrrolidinone, tetrahydrofuran, tetrahydropyran, diethyl ether, 1,4-dioxane, and isochroman have been conducted using RuCl(3)•3H(2)O/t-BuOOH in 1,2-dichloroethane. In all cases, N1 and N2 alkylation pr...

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Dades bibliogràfiques
Publicat a:ACS Catal
Autors principals: Singh, Manish K., Akula, Hari K., Satishkumar, Sakilam, Stahl, Lothar, Lakshman, Mahesh K.
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4993530/
https://ncbi.nlm.nih.gov/pubmed/27563492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.5b02603
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