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Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]...
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| Publicado no: | Acta Crystallogr E Crystallogr Commun |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Union of Crystallography
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4992926/ https://ncbi.nlm.nih.gov/pubmed/27555951 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989016009816 |
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