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Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes

Due to the high versatility of chiral cyanohydrins, the catalytic asymmetric cyanation reaction of carbonyl compounds has attracted widespread interest. However, efficient protocols that function at a preparative scale with low catalyst loading are still rare. Here, asymmetric counteranion-directed...

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Bibliografiska uppgifter
I publikationen:Nat Commun
Huvudupphovsmän: Zhang, Zhipeng, Bae, Han Yong, Guin, Joyram, Rabalakos, Constantinos, van Gemmeren, Manuel, Leutzsch, Markus, Klussmann, Martin, List, Benjamin
Materialtyp: Artigo
Språk:Inglês
Publicerad: Nature Publishing Group 2016
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4992067/
https://ncbi.nlm.nih.gov/pubmed/27530470
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms12478
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