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Catalytic enantioselective total synthesis of (+)-eucomic acid

A catalytic enantioselective synthesis of (+)-eucomic acid is reported. A palladium-catalyzed asymmetric allylic alkylation is employed to access the chiral tetrasubstituted α-hydroxyacid moiety found in the natural product. The protecting group strategy was investigated, and a protecting group mani...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Estipona, Benzi I., Pritchett, Beau P., Craig, Robert A., Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4986999/
https://ncbi.nlm.nih.gov/pubmed/27546916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2016.02.059
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