טוען...
Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals
An unprecedented NHC catalyzed annulation of enals to form 3,4-disubstituted cyclopentanones has been discovered. Aryl enals undergo dimerization in the presence of a single-electron oxidant to form C(2) symmetric cyclopentanones. A cross-reaction has also been developed, allowing for the synthesis...
שמור ב:
| הוצא לאור ב: | J Am Chem Soc |
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| Main Authors: | , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2015
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4986695/ https://ncbi.nlm.nih.gov/pubmed/26256839 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06390 |
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