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Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals
An unprecedented NHC catalyzed annulation of enals to form 3,4-disubstituted cyclopentanones has been discovered. Aryl enals undergo dimerization in the presence of a single-electron oxidant to form C(2) symmetric cyclopentanones. A cross-reaction has also been developed, allowing for the synthesis...
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| Gepubliceerd in: | J Am Chem Soc |
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| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2015
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4986695/ https://ncbi.nlm.nih.gov/pubmed/26256839 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06390 |
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