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Stereoselective synthesis of tricyclic compounds by intramolecular palladium-catalyzed addition of aryl iodides to carbonyl groups

Starting from γ-ketoesters with an o-iodobenzyl group we studied a palladium-catalyzed cyclization process that stereoselectively led to bi- and tricyclic compounds in moderate to excellent yields. Four X-ray crystal structure analyses unequivocally defined the structure of crucial cyclization produ...

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Saadi, Jakub, Bentz, Christoph, Redies, Kai, Lentz, Dieter, Zimmer, Reinhold, Reissig, Hans-Ulrich
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4979759/
https://ncbi.nlm.nih.gov/pubmed/27559374
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.118
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