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Total synthesis of leopolic acid A, a natural 2,3-pyrrolidinedione with antimicrobial activity

The first total synthesis of leopolic acid A, a fungal metabolite with a rare 2,3-pyrrolidinedione nucleus linked to an ureido dipeptide, was designed and carried out. Crucial steps for the strategy include a Dieckmann cyclization to obtain the 2,3-pyrrolidinedione ring and a Wittig olefination to i...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Dhavan, Atul A, Kaduskar, Rahul D, Musso, Loana, Scaglioni, Leonardo, Martino, Piera Anna, Dallavalle, Sabrina
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4979754/
https://ncbi.nlm.nih.gov/pubmed/27559415
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.159
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