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On the mechanism of imine elimination from Fischer tungsten carbene complexes
(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)(5)W=C(NHFc)Fc (W(CO)(5)(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)(5)W=C(OEt)Fc (M(CO)(5)(1(Et))) by ferrocenyl amide Fc-NH(–) (Fc = ferrocenyl). W(CO)(5)(E-2) thermally and photochemically elimina...
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| Udgivet i: | Beilstein J Org Chem |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4979739/ https://ncbi.nlm.nih.gov/pubmed/27559381 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.125 |
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