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Development of chiral metal amides as highly reactive catalysts for asymmetric [3 + 2] cycloadditions
Highly efficient catalytic asymmetric [3 + 2] cycloadditions using a chiral copper amide are reported. Compared with the chiral CuOTf/Et(3)N system, the CuHMDS system showed higher reactivity, and the desired reactions proceeded in high yields and high selectivities with catalyst loadings as low as...
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| Publié dans: | Beilstein J Org Chem |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4979734/ https://ncbi.nlm.nih.gov/pubmed/27559396 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.140 |
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