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Negishi Cross-Coupling Is Compatible with a Reactive B–Cl Bond: Development of a Versatile Late-Stage Functionalization of 1,2-Azaborines and Its Application to the Synthesis of New BN Isosteres of Naphthalene and Indenyl

The compatibility of the Negishi cross-coupling reaction with the versatile B–Cl functionality has been demonstrated in the context of late-stage functionalization of 1,2-azaborines. Alkyl-, aryl-, and alkenylzinc reagents have been utilized for the functionalization of the triply orthogonal precurs...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Brown, Alec N., Li, Bo, Liu, Shih-Yuan
Médium: Artigo
Jazyk:Inglês
Vydáno: 2015
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4972094/
https://ncbi.nlm.nih.gov/pubmed/26148959
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05879
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