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Dirhodium(II)-Catalyzed Annulation of Enoldiazoacetamides with α-Diazoketones: An Efficient and Highly Selective Approach to Fused and Bridged Ring Systems

A dirhodium(II)-catalyzed annulation reaction between two structurally different diazocarbonyl compounds furnishes the donor–acceptor cyclopropane-fused benzoxa[3.2.1]octane scaffold with excellent chemo-, regio-, and diastereoselectivity under exceptionally mild conditions. The composite transforma...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Cheng, Qing-Qing, Yedoyan, Julietta, Arman, Hadi, Doyle, Michael P.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4970222/
https://ncbi.nlm.nih.gov/pubmed/27006138
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601260
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