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Oxidative conversion of a Eu(II)-based T(1) agent to a Eu(III)-based paraCEST agent can be detected in vivo by MRI

In this work, we demonstrate that Eu(II) complex of DOTA-tetra(glycinate) has a higher reduction potential than most Eu(II) chelates reported so far. The reduced Eu(II) form acts as an efficient water proton T(1) relaxation reagent while the Eu(III) form acts as a water-based CEST agent. The complex...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Funk, Alexander M., Jordan, Veronica Clavijo, Sherry, A. Dean, Ratnakar, S. James, Kovacs, Zoltan
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4955383/
https://ncbi.nlm.nih.gov/pubmed/26954661
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511649
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