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Ligand-Promoted C(sp(3))–H Olefination en Route to Multi-functionalized Pyrazoles()
A Pd-catalyzed/N-heterocycle-directed C(sp(3))–H olefination has been developed. The monoprotected amino acid ligand (MPAA) is found to significantly promote Pd-catalyzed C(sp(3))–H olefination for the first time. Cu(OAc)(2) instead of Ag(+) salts are used as the terminal oxidant. This reaction prov...
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| Veröffentlicht in: | Chemistry |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4944759/ https://ncbi.nlm.nih.gov/pubmed/26991450 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600704 |
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