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Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza-o-xylylenes via the Unprecedented [2+4] Reaction Topology

A new method for photoinduced dearomatization of arenes via an intramolecular cycloaddition with aza-o-xylylenes generated by the excited-state intramolecular proton transfer (ESIPT) in the readily available photoprecursors is developed. The topology of this cycloaddition, [2+4], is unprecedented fo...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kuznetsov, Dmitry M., Mukhina, Olga A., Kutateladze, Andrei G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4943229/
https://ncbi.nlm.nih.gov/pubmed/27097759
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201602288
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