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X-ray-induced catalytic active-site reduction of a multicopper oxidase: structural insights into the proton-relay mechanism and O(2)-reduction states
During X-ray data collection from a multicopper oxidase (MCO) crystal, electrons and protons are mainly released into the system by the radiolysis of water molecules, leading to the X-ray-induced reduction of O(2) to 2H(2)O at the trinuclear copper cluster (TNC) of the enzyme. In this work, 12 cryst...
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| Publicado no: | Acta Crystallogr D Biol Crystallogr |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Union of Crystallography
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4934174/ https://ncbi.nlm.nih.gov/pubmed/26627648 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1399004715018714 |
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