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Synergistic Ion-Binding Catalysis Demonstrated via an Enantioselective, Catalytic [2,3]-Wittig Rearrangement

[Image: see text] Sigmatropic rearrangements number among the most powerful complexity-building transformations in organic synthesis but have remained largely insensitive to enantioselective catalysis due to the diffuse nature of their transition structures. Here, we describe a synergistic ion-bindi...

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Bibliografiske detaljer
Udgivet i:ACS Cent Sci
Main Authors: Kennedy, C. Rose, Guidera, Jennifer A., Jacobsen, Eric N.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2016
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4919771/
https://ncbi.nlm.nih.gov/pubmed/27413786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00125
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