Crystal structure of tetra­kis­[μ(2)-2-(di­methyl­amino)­ethano­lato-κ(3) N,O:O]di-μ(3)-hydroxido-di­thio­cyanato-κ(2) N-dichromium(III)dilead(II) di­thio­cyanate aceto­nitrile monosolvate

The tetra­nuclear complex cation of the title compound, [Cr(2)Pb(2)(NCS)(2)(OH)(2)(C(4)H(10)NO)(4)](SCN)(2)·CH(3)CN, lies on an inversion centre. The main structural feature of the cation is a distorted seco-norcubane Pb(2)Cr(2)O(6) cage with a central four-membered Cr(2)O(2) ring. The Cr(III) ion i...

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Publicat a:Acta Crystallogr E Crystallogr Commun
Autors principals: Rusanova, Julia A., Semenaka, Valentyna V., Omelchenko, Irina V.
Format: Artigo
Idioma:Inglês
Publicat: International Union of Crystallography 2016
Matèries:
Research Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4910341/
https://ncbi.nlm.nih.gov/pubmed/27375871
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989016003996
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