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Ring-strain release in neutral and dicationic 7,8,17,18-tetrabromo-5,10,15,20-tetraphenylporphyrin: crystal structures of C(44)H(26)Br(4)N(4) and C(44)H(28)Br(4)N(4) (2+)·2ClO(4) (−)·3CH(2)Cl(2)
Two porphyrin complexes were studied to determine the effects of protonation on ring deformation within the porphyrin. The porphyrin 7,8,17,18-tetrabromo-5,10,15,20-tetraphenylporphyrin, C(44)H(26)Br(4)N(4), was selected because the neutral species is readily doubly protonated to yield a dication...
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| Publicado no: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Union of Crystallography
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4908563/ https://ncbi.nlm.nih.gov/pubmed/27308051 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989016007349 |
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