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Cationic Pd(II)-catalyzed C–H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies

Cationic palladium(II) complexes have been found to be highly reactive towards aromatic C–H activation of arylureas at room temperature. A commercially available catalyst [Pd(MeCN)(4)](BF(4))(2) or a nitrile-free cationic palladium(II) complex generated in situ from the reaction of Pd(OAc)(2) and HB...

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Détails bibliographiques
Publié dans:Beilstein J Org Chem
Auteurs principaux: Nishikata, Takashi, Abela, Alexander R, Huang, Shenlin, Lipshutz, Bruce H
Format: Artigo
Langue:Inglês
Publié: Beilstein-Institut 2016
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4902085/
https://ncbi.nlm.nih.gov/pubmed/27340491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.99
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