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Scope and mechanism of the highly stereoselective metal-mediated domino aldol reactions of enolates with aldehydes
A one-pot transformation, which involves the reaction of ketones with aldehydes in the presence of metal halides to furnish tetrahydro-2H-pyran-2,4-diols in a highly diastereoselective manner, is investigated thoroughly by experiments and computations. The reaction was also successfully implemented...
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| Publicado en: | Beilstein J Org Chem |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Beilstein-Institut
2016
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4902021/ https://ncbi.nlm.nih.gov/pubmed/27340472 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.80 |
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