Ligand-induced substrate steering and reshaping of [Ag(2)(H)](+) scaffold for selective CO(2) extrusion from formic acid

Metalloenzymes preorganize the reaction environment to steer substrate(s) along the required reaction coordinate. Here, we show that phosphine ligands selectively facilitate protonation of binuclear silver hydride cations, [LAg(2)(H)](+) by optimizing the geometry of the active site. This is a key s...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Zavras, Athanasios, Khairallah, George N., Krstić, Marjan, Girod, Marion, Daly, Steven, Antoine, Rodolphe, Maitre, Philippe, Mulder, Roger J., Alexander, Stefanie-Ann, Bonačić-Koutecký, Vlasta, Dugourd, Philippe, O'Hair, Richard A. J.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4897753/
https://ncbi.nlm.nih.gov/pubmed/27265868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms11746
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