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The Z′ = 12 superstructure of Λ-cobalt(III) sepulchrate trinitrate governed by C—H⋯O hydrogen bonds

Λ-Cobalt(III) sepulchrate trinitrate crystallizes in P6(3)22 with Z = 2 (Z′ = 1/6) at room temperature. Slabs perpendicular to the hexagonal axis comprise molecules Co(sepulchrate) alternating with nitrate groups A and B. Coordinated by six sepulchrate molecules, highly disordered nitrate groups C a...

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Publicat a:Acta Crystallogr B Struct Sci Cryst Eng Mater
Autors principals: Dey, Somnath, Schönleber, Andreas, Mondal, Swastik, Prathapa, Siriyara Jagannatha, van Smaalen, Sander, Larsen, Finn Krebs
Format: Artigo
Idioma:Inglês
Publicat: International Union of Crystallography 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4886617/
https://ncbi.nlm.nih.gov/pubmed/27240768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2052520616005503
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