Stepwise Polychlorination of 8-Chloro-BODIPY and Regioselective Functionalization of 2,3,5,6,8-Pentachloro-BODIPY

An effective, stepwise methodology for polychlorination of BODIPY using trichloroisocyanuric acid (TCCA) in acetic acid was developed. In this way, selectively substituted di-, tri-, tetra-, and pentachloro-BODIPYs 2–5 were prepared. The pentachloro-BODIPY is shown to undergo regioselective Pd(0)-ca...

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Bibliographic Details
Published in:J Org Chem
Main Authors: Zhao, Ning, Xuan, Sunting, Fronczek, Frank R., Smith, Kevin M., Vicente, M. Graça H.
Format: Artigo
Language:Inglês
Published: 2015
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4881425/
https://ncbi.nlm.nih.gov/pubmed/26186141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01147
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