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Binuclear CuA Formation in Biosynthetic Models of Cu(A) in Azurin Proceeds via a Novel Cu(Cys)(2)His Mononuclear Copper Intermediate
Cu(A) is a binuclear electron transfer (ET) center found in cytochrome c oxidases (CcOs), nitrous oxide reductases (N(2)ORs), and nitric oxide reductase (NOR). In these proteins, the Cu(A) centers facilitate efficient ET (k(ET) > 10(4) s(−1)) under low thermodynamic driving forces (10–90 mV). Whi...
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| Publicado no: | Biochemistry |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4877033/ https://ncbi.nlm.nih.gov/pubmed/26352296 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b00659 |
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