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Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

Polymetalated aromatic compounds are particularly challenging synthetic goals because of the limited thermodynamic stability of polyanionic species arising from strong electrostatic repulsion between adjacent carbanionic sites. Here we describe a facile synthesis of two polyaurated complexes includi...

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Publicat a:Nat Commun
Autors principals: Yuan, Jun, Sun, Tingting, He, Xin, An, Ke, Zhu, Jun, Zhao, Liang
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4873667/
https://ncbi.nlm.nih.gov/pubmed/27186982
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms11489
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