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Oxyl and Hydroxyl Radical Transfer in mARC Catalyzed Nitrite Reduction

A combination of EPR spectroscopy and computational approaches has provided insight in to the nature of the reaction coordinate for the one-electron reduction of nitrite by the mitochondrial amidoxime reductase component (mARC) enzyme The results show that a paramagnetic Mo (V) species is generated...

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Publicat a:J Am Chem Soc
Autors principals: Yang, Jing, Giles, Logan J., Ruppelt, Christian, Mendel, Ralf R., Bittner, Florian, Kirk, Martin L.
Format: Artigo
Idioma:Inglês
Publicat: 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4872596/
https://ncbi.nlm.nih.gov/pubmed/25897643
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01112
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