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Oxyl and Hydroxyl Radical Transfer in mARC Catalyzed Nitrite Reduction
A combination of EPR spectroscopy and computational approaches has provided insight in to the nature of the reaction coordinate for the one-electron reduction of nitrite by the mitochondrial amidoxime reductase component (mARC) enzyme The results show that a paramagnetic Mo (V) species is generated...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4872596/ https://ncbi.nlm.nih.gov/pubmed/25897643 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01112 |
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