Demonstration That the Radical S-Adenosylmethionine (SAM) Enzyme PqqE Catalyzes de Novo Carbon-Carbon Cross-linking within a Peptide Substrate PqqA in the Presence of the Peptide Chaperone PqqD

The radical S-adenosylmethionine (SAM) protein PqqE is predicted to function in the pyrroloquinoline quinone (PQQ) biosynthetic pathway via catalysis of carbon-carbon bond formation between a glutamate and tyrosine side chain within the small peptide substrate PqqA. We report here that PqqE activity...

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Detalhes bibliográficos
Publicado no:J Biol Chem
Main Authors: Barr, Ian, Latham, John A., Iavarone, Anthony T., Chantarojsiri, Teera, Hwang, Jennifer D., Klinman, Judith P.
Formato: Artigo
Idioma:Inglês
Publicado em: American Society for Biochemistry and Molecular Biology 2016
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Reports
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4861456/
https://ncbi.nlm.nih.gov/pubmed/26961875
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.C115.699918
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