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Thioetherification via Photoredox/Nickel Dual Catalysis

[Image: see text] Hypervalent alkylsilicates represent new and readily accessible precursors for the generation of alkyl radicals under photoredox conditions. Alkyl radicals generated from such silicates serve as effective hydrogen atom abstractors from thiols, furnishing thiyl radicals. The reactiv...

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Publicat a:Org Lett
Autors principals: Jouffroy, Matthieu, Kelly, Christopher B., Molander, Gary A.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2016
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4854196/
https://ncbi.nlm.nih.gov/pubmed/26852821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00208
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