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Origin of Water-Induced Fluorescence Turn-On from a Schiff Base Compound: AIE or H-Bonding Promoted ESIPT?

A nonfluorescent Schiff base compound (4) in an aprotic solvent (e.g., CH(3)CN) is found to give blue fluorescence turn-on (λ(em) ≈ 475 nm) upon addition of H(2)O. By using a wide range of spectroscopic methods, including (1)H NMR and dynamic light scattering, the fluorescence response is shown to b...

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Publicado en:J Phys Chem B
Main Authors: McDonald, Lucas, Wang, Junfeng, Alexander, Nick, Li, Hui, Liu, Tianbo, Pang, Yi
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4844177/
https://ncbi.nlm.nih.gov/pubmed/26761400
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.5b10909
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