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Active sites and mechanisms for H(2)O(2) decomposition over Pd catalysts
A combination of periodic, self-consistent density functional theory (DFT-GGA-PW91) calculations, reaction kinetics experiments on a SiO(2)-supported Pd catalyst, and mean-field microkinetic modeling are used to probe key aspects of H(2)O(2) decomposition on Pd in the absence of cofeeding H(2). We c...
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| Publicado no: | Proc Natl Acad Sci U S A |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4833276/ https://ncbi.nlm.nih.gov/pubmed/27006504 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1602172113 |
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