Palladium(II)‐Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox‐Neutral, Phosphine‐Free Transformation

A redox‐neutral palladium(II)‐catalyzed conversion of aryl, heteroaryl, and alkenyl boronic acids into sulfinate intermediates, and onwards to sulfones and sulfonamides, has been realized. A simple Pd(OAc)(2) catalyst, in combination with the sulfur dioxide surrogate 1,4‐diazabicyclo[2.2.2]octane bi...

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Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Deeming, Alex S., Russell, Claire J., Willis, Michael C.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: WILEY‐VCH Verlag 2015
Gaiak:
Communications
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4832823/
https://ncbi.nlm.nih.gov/pubmed/26596861
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508370
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