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Remote Meta-C–H Activation Using a Pyridine-Based Template: Achieving Site-Selectivity via the Recognition of Distance and Geometry

[Image: see text] The pyridyl group has been extensively employed to direct transition-metal-catalyzed C–H activation reactions in the past half-century. The typical cyclic transition states involved in these cyclometalation processes have only enabled the activation of ortho-C–H bonds. Here, we rep...

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Detalhes bibliográficos
Publicado no:ACS Cent Sci
Main Authors: Chu, Ling, Shang, Ming, Tanaka, Keita, Chen, Qinghao, Pissarnitski, Natalya, Streckfuss, Eric, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4827496/
https://ncbi.nlm.nih.gov/pubmed/27162997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.5b00312
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