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Formation of Hg(II) Tetrathiolate Complexes with Cysteine at Neutral pH
Mercury(II) ions precipitate from aqueous cysteine (H(2)Cys) solutions containing H(2)Cys/Hg(II) mole ratio ≥ 2.0 as Hg(S-HCys)(2). In absence of additional cysteine, the precipitate dissolves at pH ~12 with the [Hg(S,N-Cys)(2)](2−) complex dominating. With excess cysteine (H(2)Cys/Hg(II) mole ratio...
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| Publicado no: | Can J Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4824553/ https://ncbi.nlm.nih.gov/pubmed/27064521 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1139/cjc-2015-0375 |
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