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Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce–Smiles Rearrangement
A new benzyne transformation is described that affords versatile biaryl structures without recourse to transition‐metal catalysis or stoichiometric amounts of organometallic building blocks. Aryl sulfonamides add to benzyne upon fluoride activation, and then undergo an aryl Truce–Smiles rearrangemen...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4819888/ https://ncbi.nlm.nih.gov/pubmed/26762551 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201510236 |
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