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Diastereomeric resolution directed towards chirality determination focussing on gas-phase energetics of coordinated sodium dissociation
Defining chiral centres is addressed by introducing a pair of chiral auxiliary groups. Ions of diastereomeric pairs of molecules could be distinguished utilising energy-resolved mass spectrometry, and the applicability of the method to a series of compounds carrying amine, carboxylic acid, alcohol,...
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Publicado no: | Sci Rep |
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Main Authors: | , , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Nature Publishing Group
2016
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4819175/ https://ncbi.nlm.nih.gov/pubmed/27040078 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep24005 |
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