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Natural Diels-Alderases: Elusive and Irresistable

Eight examples of biosynthetic pathways wherein a natural enzyme has been identified and claimed to function as a catalyst for the [4+2] cycloaddition reaction, namely, Diels-Alderases, are briefly reviewed. These are discussed in the context of the mechanistic challenges associated with the technic...

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Publicado en:J Org Chem
Autores principales: Klas, Kimberly, Tsukamoto, Sachiko, Sherman, David H., Williams, Robert M.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2015
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4806863/
https://ncbi.nlm.nih.gov/pubmed/26495876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01951
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