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Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere
The [FeFe] hydrogenases (H(2)ases) catalyze the redox reaction that interconverts protons and H(2). This area of biocatalysis has attracted attention because the metal-based chemistry is unusual, and the reactions have practical implications. The active site consists of a [4Fe–4S] cluster bridged to...
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| Pubblicato in: | Acc Chem Res |
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| Autore principale: | |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4797653/ https://ncbi.nlm.nih.gov/pubmed/26079848 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00177 |
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