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Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst

[Image: see text] A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF(6) as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Miller, Ricarda, Carreras, Javier, Muratore, Michael E., Gaydou, Morgane, Camponovo, Francesco, Echavarren, Antonio M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4782180/
https://ncbi.nlm.nih.gov/pubmed/26839084
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b02607
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