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Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates

Palladium-catalyzed ring-opening reactions of C1 substituted 7-oxanorbornadiene derivatives with aryl iodides were investigated. The optimal conditions for this reaction were found to be PdCl(2)(PPh(3))(2), ZnCl(2), Et(3)N and Zn in THF. Both steric and electronic factors played a role in the outcom...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Edmunds, Michael, Raheem, Mohammed Abdul, Boutin, Rebecca, Tait, Katrina, Tam, William
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4778517/
https://ncbi.nlm.nih.gov/pubmed/26977182
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.25
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