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Amino-functionalized (meth)acryl polymers by use of a solvent-polarity sensitive protecting group (Br-t-BOC)

We describe the synthesis of bromo-tert-butyloxycarbonyl (Br-t-BOC)-amino-protected monomers 2-((1-bromo-2-methylpropan-2-yl)oxycarbonylamino)ethyl (meth)acrylate 3a,b. For this purpose, 2-isocyanatoethyl (meth)acrylate 1a,b was reacted with 1-bromo-2-methylpropan-2-ol (2a). The free radical polymer...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Ritter, Helmut, Tabatabai, Monir, Herrmann, Markus
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4778502/
https://ncbi.nlm.nih.gov/pubmed/26977183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.26
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