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Temporal Control of Gelation and Polymerization Fronts Driven by an Autocatalytic Enzyme Reaction

Chemical systems that remain kinetically dormant until activated have numerous applications in materials science. Herein we present a method for the control of gelation that exploits an inbuilt switch: the increase in pH after an induction period in the urease‐catalyzed hydrolysis of urea was used t...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Jee, Elizabeth, Bánsági, Tamás, Taylor, Annette F., Pojman, John A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4755207/
https://ncbi.nlm.nih.gov/pubmed/26732469
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201510604
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