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Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide‐Derived Copper

Oxide‐derived copper (OD‐Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at −0.3 V (vs. RHE). By using static headspace‐gas chromatography for liquid phase analysis, we identify acetaldehyde as a mino...

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Veröffentlicht in:Angew Chem Int Ed Engl
Hauptverfasser: Bertheussen, Erlend, Verdaguer‐Casadevall, Arnau, Ravasio, Davide, Montoya, Joseph H., Trimarco, Daniel B., Roy, Claudie, Meier, Sebastian, Wendland, Jürgen, Nørskov, Jens K., Stephens, Ifan E. L., Chorkendorff, Ib
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2015
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4737304/
https://ncbi.nlm.nih.gov/pubmed/26692282
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508851
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