An Unexpected Controlled New Oxidant: SO(4)(.–)

A controlled new oxidant sulfate radical anion (SO(4)(.–)) was found and it can be easily prepared by mixing Na(2)S(2)O(4) and TBHP with stirring. In this new metal-free oxidation system (Na(2)S(2)O(4)/TBHP), SO(4)(.–) can be used as a controllable oxidant to oxidize various aromatic alcohols to the...

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Publicado no:Sci Rep
Principais autores: Bai, Cui-Bing, Wang, Nai-Xing, Lan, Xing-Wang, Wang, Yan-Jing, Xing, Yalan, Wen, Jia-Long, Gao, Xue-Wang, Zhang, Wei
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4735593/
https://ncbi.nlm.nih.gov/pubmed/26832822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep20163
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