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Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes

Oxidation of 3- and 4-pentafluorosulfanyl-substituted anisoles and phenols with hydrogen peroxide and sulfuric acid provided a mixture of SF(5)-substituted muconolactone, maleic, and succinic acids. A plausible mechanism for the formation of the aliphatic SF(5) compounds was presented and their chem...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Vida, Norbert, Václavík, Jiří, Beier, Petr
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4734437/
https://ncbi.nlm.nih.gov/pubmed/26877813
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.12
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